Chem 3B help please... test on Monday FML.

<p>how many products for the last page diels alder?</p>

<p>what did you guys put for the synthesis problems?</p>

<p>how long does it take for pedersen to grade them?</p>

<p>For the first synthesis I put Friedel Crafts Acylation to put on the carbons than used LAH to make an anion oxygen and than H+/H2O. For the second one I made a Diels-Alder than ozonolysis. What about you guys?</p>

<p>i put 2 for the last page diels alder, i don’t really remember the first synthesis problem but i know i had 2 steps and the second was NaBh4/MeOH. I think the first was Friedl Crafts acylation actually. Second synthesis was diels alder then ozonolysis?</p>

<p>what was your diene?</p>

<p>oh awesome calbear haha pretty much exactly the same</p>

<p>pentyl group sticking off of the diene? lol</p>

<p>How did you guys do the catalytic I2 reaction?</p>

<p>made the double bond grab an I and make an allylic cation then switch it to trans and make another I take the I away and remake the double bond hahaha. no idea if that’s right.</p>

<p>Thats what I did, and I was so mind****ed that it would be that easy…</p>

<p>oh what did you guys do for the BF3 thing?</p>

<p>make the BF3 just fall off at the end so you get an alcohol? or is that completely wrong.</p>

<p>I used the O-BF3 bond to take the hydrogen, just like the Cl-AlCL3 bond takes away the H to regain aromaticity in the ring.</p>

<p>Nomenclature for the thiosulfonate?</p>

<p>diallyl thiosulfonate?
i forgot to write trans when naming that ridiculously long aldehyde thing -_________-</p>

<p>The last Diels alder on the last page should have 4 posssibilities right? Cis and trans</p>

<p>uhhh cis and trans what
pretty sure the pentyl group with the N is never going to be trans if that’s what you mean…?</p>

<p>Cis and trans to the ketone looking things. Both up or down or opposite</p>

<p>I also put diallyl thiosulfinate and yeah I also made the O-BF3 take the hydrogen to reform the benzene ring and the alcohol, but I just did that because nothing else could take it right?</p>

<p>i love how this thread is one of the longest on the Berkeley forum and it’s only been up for 2 days</p>

<p>fantastic, lecture in 7 hours…i haven’t smoked pot in a long time…im getting a good reason to start up again this weekend :D:D</p>

<p>Oh geez after my physics midterm on Thursday people are gonna mistaken my apartment for a steaming volcano that’s about to erupt.</p>