Toured W&M and Wake. Neither is in an urban setting by any definition. W&M’s town is very, very small. We drove west to Newport News to try to check out the closest near city; it was not a quick drive.
Wake is also not urban. It’s a defined college campus with wide open lawns, close to, but not within (for practical matters) the city of Winston Salem.
You’re in Ohio, Ohio State is an example of urban, as in the city is a short bike ride away, campus edges on to downtownish areas, things like that. If you are interested not only in urban settings but colleges with a decent size city close by, that’s fine, they are just two separate things!
LMU in LA seems to check all of your boxes, my daughter goes there. (I don’t know about “prestige”, we didn’t really factor that in, but is is a fine school and Jesuit schools are usually very well regarded in that mid size range.