Will Early Decision to a University Effect Admissions of Early Action Applications to others?

No, the schools do not share info on who is applying.
As long as VTech allows EA applications to other schools, then you should be good.

In fact, many students apply early to multiple colleges as long as it does not violate any rules of the ED college.
If you get admitted to VT in ED, you will have to decline other acceptances (barring financial reasons)