(For) any mayor of a vast area , an (understanding of) current issues in all districts (is) not only (desirous) but also vital .
For me i see that d that no problem i know that it is a case of parallelism what come after (not only) must comes also after (but also) . ( Desirous) is adj and ( vital ) is also is adj so it is correct parallel structure .
Looking at the examples on that dictionary page, however, it seems that its meaning is not quite “desirable.”
Ex. She is desirous of…
Means “She desires…” not “She is desirable.”
You can think of it as “desirous” being subjective and “desirable” being objective. So you can be desirable to your parents, but desirous of chocolate.