<p>So now we know that the answer is PdV … which is -4.6 * 10^-3 L<em>atm</em>mol^-1</p>
<p>What we want, however, is J<em>mol^-1, so you need to convert L</em>atm to J. We take the two R factors given, 8.314 J<em>mol^-1</em>K^-1 and 0.0821 L<em>atm</em>mol^-1<em>K^-1 and take the first over the second, giving you 101.3 J</em>L^-1<em>atm^-1. We then multiply this by the PdV, so -4.6 * 10^-3 L</em>atm<em>mol^-1 * 101.3 J</em>L^-1<em>atm^-1 and including units this yields -4.7 * 10^-1 J</em>mol^-1, so the answer is A.</p>
<p>That paragraph is so hard to read… oh well.</p>
<p>I didn’t do USACHO last year. Based on the practice tests, I thought the FRQ this year was def harder this year. Multiple choice I thought was about the same.</p>